Organic compounds -- part of the class 532-570 series – Organic compounds – Sulfonate esters
Reexamination Certificate
2007-12-25
2007-12-25
Keys, Rosalynd (Department: 1621)
Organic compounds -- part of the class 532-570 series
Organic compounds
Sulfonate esters
C570S128000, C570S185000, C570S237000, C548S373100, C548S376100
Reexamination Certificate
active
10751844
ABSTRACT:
The invention relates to a process for preparing arylvinyl halides and sulphonates and arylalkynes by reacting haloaromatics or aryl sulphonates with vinyl halides or sulphonates in the presence of a palladium catalyst and a base and, if appropriate, subsequent elimination.
REFERENCES:
patent: 3848010 (1974-11-01), Intille
patent: 5300521 (1994-04-01), Eberle et al.
patent: 5541213 (1996-07-01), Matsukura et al.
patent: 5606073 (1997-02-01), Matsukura et al.
patent: 5703269 (1997-12-01), Herrmann et al.
patent: 6005151 (1999-12-01), Herrmann et al.
patent: 6019986 (2000-02-01), Banks
patent: 6090394 (2000-07-01), Banks
patent: 6214852 (2001-04-01), Kim et al.
patent: 6255333 (2001-07-01), Banks
patent: 6316675 (2001-11-01), Reetz et al.
patent: 6392053 (2002-05-01), Chen et al.
patent: 6414156 (2002-07-01), Chen et al.
patent: 6515004 (2003-02-01), Misra et al.
patent: 6534531 (2003-03-01), Kimball et al.
patent: 6613911 (2003-09-01), Chen et al.
patent: 6639074 (2003-10-01), Chen et al.
patent: 2001/0004639 (2001-06-01), Chen et al.
patent: 2001/0006976 (2001-07-01), Chen et al.
patent: 2001/0019780 (2001-09-01), Obata et al.
patent: 2002/0058810 (2002-05-01), Talley et al.
patent: 2002/0061915 (2002-05-01), Kimball et al.
patent: 2002/0072609 (2002-06-01), Chen et al.
patent: 2002/0099217 (2002-07-01), Chen et al.
patent: 2002/0156115 (2002-10-01), Oda et al.
patent: 2002/0173662 (2002-11-01), Banks
patent: 2003/0191171 (2003-10-01), Oda et al.
patent: 2003/0216440 (2003-11-01), Chen et al.
patent: 2004/0063767 (2004-04-01), Chen et al.
patent: 719758 (1996-07-01), None
patent: 1008601 (2000-06-01), None
patent: 1260270 (2002-11-01), None
patent: 2001-294541 (2001-10-01), None
patent: 93/01173 (1993-01-01), None
patent: 98/42644 (1998-10-01), None
patent: 02/10093 (2002-02-01), None
Chem. Ber., 115, (month unavailable) 1982, p. 828-831, H. J. Bestmann et al, “Reaktionen mit Phosphinalkylenen, XL1,2)”, no translation.
Chem. Ber., 98 (month unavailable) 1965, p. 3554-3560, K. Bodendorf et al, “Über die Darstellung und Fragmentierung von β-Chlor-acroleinen”, no translation.
J. Gen. Chem. USSR, Bd. 33, (month unavailable), 1963, p. 158-162, A. V. Dombrovskii et al, “Haloarylation of Unsaturated Compounds with Aromatic Diazo Compounds. XVII. Arylation of α-Chlorostryrene and the Preparation of Tolans” XP009030547.
J. Org. Chem., 62, (month unavailable), 1997 , p. 8957-8960, E. Negishi et al, “Direct Synthesis of Terminal Alkynes via Pd-Catalyzed Cross Coupling of Aryl and Alkenyl Halides with Ethynylmetals Containing Zn, Mg, and Sn. Critical Comparison of Countercations”.
Dept. of Chem. And Biochem., vol. 3, No. 12, Apr. 1, 2001, p. 1869-1871, B. H. Lipshutz et al, “Efficient Scavenging of Ph3P and Ph3P=O with High0Loading Merrifield Resin”.
Chem. Commun., (month unavailable) 2002, p. 278-279, D. T.-Y. Bong et al, “Synthesis of bent [4]phenylene (cyclobuta[1,2-a:3,4-b′]bisbiphenylene) and structure of a bis(trimethylsilyl) derivative: the last [4]phenylene isomer”.
Chem. Pharm. Bull. 31(5), (month unavailable) 1983, p. 1751-1753, Y. Suzuki et al, “Formylation Of Phenols with Electron-withdrawing Groups in Strong Acids. Synthesis of Substituted Salicylaldehydes”.
Syn. Comm., 30(3), (month unavailable) 2000, p. 397-403, G. V. M. Sharma et al, “Synthesis Of 5-Fluoro Salicylic Acid”.
J. Org. Chem., v. 62, p. 895, Negishi Supplemental, p. 1-24, E. Negishi et al, “Direct Synthesis of Terminal . . . ”.
J. Org. Chem., v. 62, p. 895, Negishi Supplemental, p. 1-24, E. Negishi et al, “Direct Synthesis of Terminal . . . ”, 1997.
Ebenbeck Wolfgang
Rampf Florian
Keys Rosalynd
LANXESS Deutschland GmbH
Miller Michael A.
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