Process for preparing arylalkynes

Organic compounds -- part of the class 532-570 series – Organic compounds – Sulfonate esters

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C570S128000, C570S185000, C570S237000, C548S373100, C548S376100

Reexamination Certificate

active

10751844

ABSTRACT:
The invention relates to a process for preparing arylvinyl halides and sulphonates and arylalkynes by reacting haloaromatics or aryl sulphonates with vinyl halides or sulphonates in the presence of a palladium catalyst and a base and, if appropriate, subsequent elimination.

REFERENCES:
patent: 3848010 (1974-11-01), Intille
patent: 5300521 (1994-04-01), Eberle et al.
patent: 5541213 (1996-07-01), Matsukura et al.
patent: 5606073 (1997-02-01), Matsukura et al.
patent: 5703269 (1997-12-01), Herrmann et al.
patent: 6005151 (1999-12-01), Herrmann et al.
patent: 6019986 (2000-02-01), Banks
patent: 6090394 (2000-07-01), Banks
patent: 6214852 (2001-04-01), Kim et al.
patent: 6255333 (2001-07-01), Banks
patent: 6316675 (2001-11-01), Reetz et al.
patent: 6392053 (2002-05-01), Chen et al.
patent: 6414156 (2002-07-01), Chen et al.
patent: 6515004 (2003-02-01), Misra et al.
patent: 6534531 (2003-03-01), Kimball et al.
patent: 6613911 (2003-09-01), Chen et al.
patent: 6639074 (2003-10-01), Chen et al.
patent: 2001/0004639 (2001-06-01), Chen et al.
patent: 2001/0006976 (2001-07-01), Chen et al.
patent: 2001/0019780 (2001-09-01), Obata et al.
patent: 2002/0058810 (2002-05-01), Talley et al.
patent: 2002/0061915 (2002-05-01), Kimball et al.
patent: 2002/0072609 (2002-06-01), Chen et al.
patent: 2002/0099217 (2002-07-01), Chen et al.
patent: 2002/0156115 (2002-10-01), Oda et al.
patent: 2002/0173662 (2002-11-01), Banks
patent: 2003/0191171 (2003-10-01), Oda et al.
patent: 2003/0216440 (2003-11-01), Chen et al.
patent: 2004/0063767 (2004-04-01), Chen et al.
patent: 719758 (1996-07-01), None
patent: 1008601 (2000-06-01), None
patent: 1260270 (2002-11-01), None
patent: 2001-294541 (2001-10-01), None
patent: 93/01173 (1993-01-01), None
patent: 98/42644 (1998-10-01), None
patent: 02/10093 (2002-02-01), None
Chem. Ber., 115, (month unavailable) 1982, p. 828-831, H. J. Bestmann et al, “Reaktionen mit Phosphinalkylenen, XL1,2)”, no translation.
Chem. Ber., 98 (month unavailable) 1965, p. 3554-3560, K. Bodendorf et al, “Über die Darstellung und Fragmentierung von β-Chlor-acroleinen”, no translation.
J. Gen. Chem. USSR, Bd. 33, (month unavailable), 1963, p. 158-162, A. V. Dombrovskii et al, “Haloarylation of Unsaturated Compounds with Aromatic Diazo Compounds. XVII. Arylation of α-Chlorostryrene and the Preparation of Tolans” XP009030547.
J. Org. Chem., 62, (month unavailable), 1997 , p. 8957-8960, E. Negishi et al, “Direct Synthesis of Terminal Alkynes via Pd-Catalyzed Cross Coupling of Aryl and Alkenyl Halides with Ethynylmetals Containing Zn, Mg, and Sn. Critical Comparison of Countercations”.
Dept. of Chem. And Biochem., vol. 3, No. 12, Apr. 1, 2001, p. 1869-1871, B. H. Lipshutz et al, “Efficient Scavenging of Ph3P and Ph3P=O with High0Loading Merrifield Resin”.
Chem. Commun., (month unavailable) 2002, p. 278-279, D. T.-Y. Bong et al, “Synthesis of bent [4]phenylene (cyclobuta[1,2-a:3,4-b′]bisbiphenylene) and structure of a bis(trimethylsilyl) derivative: the last [4]phenylene isomer”.
Chem. Pharm. Bull. 31(5), (month unavailable) 1983, p. 1751-1753, Y. Suzuki et al, “Formylation Of Phenols with Electron-withdrawing Groups in Strong Acids. Synthesis of Substituted Salicylaldehydes”.
Syn. Comm., 30(3), (month unavailable) 2000, p. 397-403, G. V. M. Sharma et al, “Synthesis Of 5-Fluoro Salicylic Acid”.
J. Org. Chem., v. 62, p. 895, Negishi Supplemental, p. 1-24, E. Negishi et al, “Direct Synthesis of Terminal . . . ”.
J. Org. Chem., v. 62, p. 895, Negishi Supplemental, p. 1-24, E. Negishi et al, “Direct Synthesis of Terminal . . . ”, 1997.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Process for preparing arylalkynes does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for preparing arylalkynes, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for preparing arylalkynes will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3860748

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.