Process for preparing arylacetic and arylpropionic acids

Chemistry: electrical and wave energy – Processes and products

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C25B 100

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active

045170614

ABSTRACT:
The process includes an electrochemical reduction, under carbon dioxide atmosphere, of benzyl type ArCH.sub.2 X or ArCH(CH.sub.3)X halogenides.
According to the invention, the process consists of operating in the presence of a catalyst containing at least one organometallic complex derived from a transition metal combined with a bidentate or tetradentate coordinate.

REFERENCES:
patent: 3344045 (1967-09-01), Neikam
patent: 3764492 (1973-10-01), Baizer
Baizer et al., J. Org. Chem., vol. 37, No. 12, 1972, pp. 1951, 1957.
Troupel et al., Nouveau Journal of Chimie, vol. 5, No. 12 (1981) pp. 621-624.

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