Process for preparing aniline compounds from amides with rhodium

Details Process for preparing aniline compounds from amides with rhodium Process for preparing aniline compounds from amides with rhodium

1978-03-22

1979-04-03

Douglas, Winston A.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

252447, 252472, 260574, 260575, 260576, 260577, C07C 8512, B01J 2374

Patent

active

041477251

ABSTRACT:
A vapor-phase process for preparing aniline or a substituted aniline, the process comprising contacting vaporous benzamide or a vaporous substituted benzamide with a metal catalyst, is improved by using rhodium as the metal catalyst.

REFERENCES:
patent: 2880241 (1959-03-01), Hughes
patent: 3483242 (1969-12-01), Brownstein et al.
Ginsburg, "Concerning Amines", First Ed., pp. 46-52, (1967).
Astle, "Industrial Organic Nitrogen Compounds", pp. 25-26, (1961).
Sidgwick, "Organic Chemistry of Nitrogen", Third Ed., pp. 100, 101 & 235, (1966).

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