Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Selenium or tellurium or compound containing same
Patent
1984-02-07
1986-01-07
Shine, W. J.
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Selenium or tellurium or compound containing same
502309, 502338, B01J 2106, B01J 2384, B01J 2388
Patent
active
045634408
ABSTRACT:
This invention provides a catalyst composition suitable for the gas phase oxidation, ammoxidation and oxidative dehydrogenation of olefins to unsaturated aldehydes, unsaturated nitriles and dienes respectively. The catalyst composition comprises, as active catalyst component, a solid solution of Fe, Sb and Ti oxides which has a rutile type crystal structure which is present in the composition in an amount of at least 80 wt. %, and which is represented by the empirical formula Fe.sub.x Sb.sub.y Ti.sub.z O.sub.w, wherein, for x=1, y is in the range of 0.5 to 10, z is in the range of 0.16 to 209 and w represents the number of oxygen atoms corresponding to the oxides of the above elements. The catalyst component is prepared by co-precipitating metal oxides from solutions of corresponding metal salts followed by calcination at 600.degree.-1000.degree. C. of the washed and dried precipitate.
REFERENCES:
patent: 3546138 (1970-12-01), Callahan et al.
patent: 3990999 (1976-11-01), Gasson et al.
patent: 4380664 (1983-04-01), Ishii et al.
Forzatti Pio
Trifiro Ferruccio
Villa Pierluigi
Shine W. J.
Stamicarbon B.V., Licensing Subsidiary of DSM
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