Process for preparing an isotactic/syndiotactic polymer blend in

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526114, 526115, 526118, 526119, 526128, 502113, 502125, C08F 464

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056484283

ABSTRACT:
The present invention is a process for producing a polymer blend in a single reactor, specifically a polymer blend of isotactic polyolefins and syndiotactic polyolefins. The catalyst system is a combination of at least one metallocene catalyst and at least one conventional supported Ziegler-Natta catalyst. The multi-catalyst system is obtained by mixing the components of at least one metallocene catalyst and at least one conventional supported Ziegler-Natta catalyst. The metallocene catalyst comprises a metallocene compound and an ionizing agent. The conventional supported Ziegler-Natta catalyst comprises an aluminum alkyl and a transition metal compound with, optionally, an electron donor.

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J. Am. Chem. Soc. 1988, 110, 6255-6256, Ewen et al "Syndrotactic propylene polymerization with Group 4 metallocene".
International Symposium on Recent Development in Olefin polymerization Catalyst, 1988. pp. 501-515. Keii et al. "catalystic olefin polymerization".

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