Process for preparing an alternating copolymer of a conjugated v

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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260 63R, 260 795R, 526184, 526185, 526183, 526187, 526190, 526196, 526197, 526291, 526303, 526329, 526342, 526343, 526347, 526350, C08F 2800

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039898822

ABSTRACT:
An alternating copolymer of an olefinic unsaturated compound and a conjugated vinyl compound is produced by contacting said monomers with at least one organoboron halide or/and a mixture of at least one organo-compound of metal from Groups IIb, IIIb and IVb of the Mendeleev Periodic Table and at least one halogeno-compound of metal from Groups IIIb and IVb of the Mendeleev Periodic Table. A typical catalyst is ethylboron dichloride or a combination of triethylaluminum and tin tetrachloride.

REFERENCES:
patent: 3127380 (1964-03-01), Welch
patent: 3326870 (1967-06-01), Nakaguchi et al.
patent: 3578636 (1971-05-01), Nakaguchi et al.
patent: 3700648 (1972-10-01), Hirooka et al.
Zutty and Welch, J. Polymer Science, 1960, 43, pp. 445-452.
Hirooka et al., J. Polymer Science, 1973, 11, pp. 1281-1306.

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