Process for preparing an alkanone and/or alkanol

Details Process for preparing an alkanone and/or alkanol Process for preparing an alkanone and/or alkanol

1993-03-15

1994-03-29

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568311, 568385, 568835, 5689098, C07C 4553

Patent

active

052986659

ABSTRACT:
The invention relates to a process for preparing an alkanone and/or alkanol by oxidizing an alkane with 3-30 C-atoms, using oxygen, to form an alkyl hydroperoxide, followed by a decomposition of the resulting alkyl hydroperoxide in the presence of a metal compound immobilized on a carrier, which carrier carries aliphatic or aromatic amine groups or sulphide groups. The process is preferably applied to cycloalkanes.

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A. C. Banciu et al.; Oxidation of Cumene With Molecular Oxygen in Presence of Co(II) Acetylacetonate Complexes Heterogenized on Silane Modified Silica; Revue Roumaine de Chimie, 34 (1989) 1711-1720.
Ichiro Okura et al.; On the kinetics and the Mechanism of Hydrogen Peroxide Decomposition With Silica-Supported Metallo-Porphyrins; Journal of Molecular Catalysis, 5, (1979) 293-301.
Yasuhiko Kurusu and D. C. Neckers; Functionalization of Silica Gel: Application for the Catalytic Oxidation of Alkanes; 914 The Journal of Organic Chemistry 56; (91991) 1981-1983.
European Search Report, Nov. 28, 1991.

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