Process for preparing an A 2A -adenosine receptor agonist...

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbohydrates or derivatives

Reexamination Certificate

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C536S027630, C536S027700

Reexamination Certificate

active

07732595

ABSTRACT:
Disclosed is a synthesis suitable for large scale manufacture of an A2A-adenosine receptor agonist, and also relates to polymorphs of that compound, and to methods of isolating a specific polymorph. The A2A-adenosine receptor agonist has the following formula:This compound is prepared by reacting the ethyl ester with methylamine in a sealed pressure reactor.

REFERENCES:
patent: 6403567 (2002-06-01), Zablocki et al.
patent: 6642210 (2003-11-01), Zablocki et al.
patent: 7183264 (2007-02-01), Zablocki et al.
Niiya K. et al, “2-(N′-Alkylidenehydrazino) Adenosines: Potent and Selective Coronaryvasodilators”,Journal of Medicinal Chemistry, American Chemical Society. Washington, vol. 35, No. 24, 1992, pp. 4557-4561.

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