Process for preparing .alpha.-ketocarboxylic acids

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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260413, 260465F, 2604656, 546340, 546341, 549 66, 562426, 562433, 562440, 562464, 562507, 562508, 562577, 549488, C07C 5976, C07C 5980, C07C 5986, C07C 6238

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043340873

ABSTRACT:
A novel process for the manufacture of .alpha.-ketocarboxylic acids which comprises the reaction of oximinohalide with cyanide ion to form oximinonitrile which is reacted with hydroxide ion to form oximinoacid and hydrolysis thereof to the .alpha.-ketoacid.

REFERENCES:
patent: 3254109 (1966-05-01), Hartle
patent: 3897467 (1975-07-01), Anatol
patent: 4234739 (1980-11-01), Photis
Davies, J. H. et al., J. Chem. Soc. (C), pp. 431-435, 1968.

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