Process for preparing allylsilane compound derivatives

Details Process for preparing allylsilane compound derivatives Process for preparing allylsilane compound derivatives

1997-06-05

1998-07-14

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

556427, 556488, C07F 708

Patent

active

057806616

ABSTRACT:
Allyl silane compounds represented by the formula (CH.sub.2 .dbd.CH--CH.sub.2 --)R.sub.n SiCl.sub.3-n (R represents, independently of each other, hydrocarbon groups with a carbon number of C.sub.1 to C.sub.8 ; n represents an integer from 0 to 3) are reacted with AX (AX stands for mercaptans, thiocarboxylic acids, carbon tetrachloride, or chloroform, the letter X represents, respectively, H bonded to sulfur in the case of mercaptans and thiocarboxylic acids, chlorine in the case of carbon tetrachloride, and H in the case of chloroform, and the letter A represents a residual group bonded to X) in the presence of radical generating agents, thereby obtaining allylsilane compounds represented by the formula (ACH.sub.2 CHXCH.sub.2)R.sub.n SiCl.sub.3-n (R, n, A and X have the same meaning as above).

REFERENCES:
patent: 3686326 (1972-08-01), Oswald et al.
patent: 3859360 (1975-01-01), Oswald et al.
Ojima, Iwao, "The hydrosilylation reaction," The Chmistry of Organic Silicon Compounds, 1989, pp. 1479-1527.
Colvin, Ernest, "Silicon Reagents in Organic Synthesis," Academic Press, 1988, pp. 21-49.
Mironov,V.F., "Orientation of addition of HBr and HI to allyl-and methallylsilane chlorides," Izvest. Akad. Nauk S.S.S.R., 1959 (10)1862 and abstracts.

Affiliated with

Also associated with

Rating

Process for preparing allylsilane compound derivatives does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Process for preparing allylsilane compound derivatives, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Process for preparing allylsilane compound derivatives will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1883223