Process for preparing allylic esters of carboxylate acids and al

Details Process for preparing allylic esters of carboxylate acids and al Process for preparing allylic esters of carboxylate acids and al

1974-02-04

1976-06-22

Weinberger, Lorraine A.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260632C, 260635R, 2604109N, C07C 6700

Patent

active

039651541

ABSTRACT:
A process for preparing allylic esters of carboxylic acids and allylic alcohols which comprises reacting a mixture of a lower alkyl carboxylate ester, water, and the corresponding carboxylic acid and alcohol with an olefin having an allylic carbon-hydrogen bond and oxygen in the presence of a catalyst system comprising an oxidation catalyst and an acidic co-catalyst.

REFERENCES:
patent: 2428590 (1947-10-01), Shokal
patent: 3306930 (1967-02-01), Copelin et al.
patent: 3346624 (1967-10-01), Schaeffer et al.
patent: 3444189 (1969-05-01), Olivier
patent: 3668257 (1972-06-01), Schaeffer
patent: 3670014 (1972-06-01), Fernholz
Boutry et al., Jour. of Catalysis, 23, pp. 19-30, (1971).

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