Process for preparing alkylene carbonates from alkylene oxides

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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C07D31712

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049315714

ABSTRACT:
An alkylene oxide, e.g. ethylene oxide, is prepared from the corresponding alkylene carbonate, e.g. ethylene carbonate, in the presence of an effective amount of a quaternary arsonium halide. The quaternary arsonium halides are also effective catalysts for the reverse reaction, that is, to form alkylene carbonates from the corresponding epoxide and carbon dioxide.

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patent: 3535342 (1970-10-01), Emmons
patent: 4226778 (1980-10-01), Venturello et al.
patent: 4841072 (1989-06-01), Harvey

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