Process for preparing alkyl halides

Details Process for preparing alkyl halides Process for preparing alkyl halides

1988-07-28

1990-06-19

Mars, Howard T.

Organic compounds -- part of the class 532-570 series

Organic compounds

Halogen containing

570142, C07C 1716

Patent

active

049355643

ABSTRACT:
A process for preparation of an alkyl halide, RX, from reaction between the corresponding alcohol, ROH, and a hydrogen halide, HX, which improves conversion of the hydrogen halide to the alkyl halide in a single pass through a reactor. The process comprises (A) contacting and reacting the hydrogen halide with a stoichiometric excess of the alcohol in a plug-flow reactor in which flow of a mixture comprising unreacted alcohol, unreacted hydrogen halide, the alkyl halide, and water is co-current; and (B) isolating and separating the alkyl halide.

REFERENCES:
patent: 1918371 (1933-07-01), Berndt et al.
patent: 2570495 (1946-08-01), Scott

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