Process for preparing alkoxylated alkyl glyceryl ether sulfonate

Organic compounds -- part of the class 532-570 series – Organic compounds – Sulfonic acids or salts thereof

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C07C30900

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056211392

ABSTRACT:
A continuous process for preparing alkoxylated alkyl glyceryl ether sulfonates which comprises reacting in the presence of water a mixture of an alkali metal sulfide and bisulfite with a mixture of alkoxylated glycidyl ethers comprising a major quantity of a ##STR1## wherein R is alkyl or alkenyl of about eight to twenty carbon atoms, R' is H or methyl, n is an average integer value of 1 to about 12 to obtain alkoxylated sulfonated product having as a major quantity of the alkoxylated product ##STR2## at an elevated temperatures of at least 125.degree. C., a pressure sufficient to maintain the reaction mass liquid at the reaction temperature and at least 20 wt % of the reaction mass as sulfonated product.

REFERENCES:
patent: 2989547 (1961-06-01), Whyte et al.
patent: 3024273 (1962-03-01), Whyte et al.
patent: 3228979 (1966-01-01), Gaertner
patent: 4502538 (1985-03-01), Wellington et al.
patent: 5310508 (1994-05-01), Subramanyam et al.
Whyte, Alkyl Glyceryl Ether Sulfonates, Surfactant Science Series, vol. 7, Anionic Surfactants, part 2, pp. 483-494.

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