Process for preparing alkanols from synthesis gas

Details Process for preparing alkanols from synthesis gas Process for preparing alkanols from synthesis gas

1981-10-29

1982-12-07

Mars, Howard T.

Chemistry: fischer-tropsch processes; or purification or recover

Liquid phase fischer-tropsch reaction

252428, C07C 2706

Patent

active

043628214

ABSTRACT:
This invention concerns a process of making alkanols and particularly methanol which comprises reacting a mixture of CO and H.sub.2 at a pressure of about 500 psig or greater and at a temperature of at least 150.degree. C. in the presence of a catalyst system comprising a ruthenium-containing compound and a rhenium- or manganese-containing compound and a quaternary phosphonium or ammonium base or salt and in the presence of an inert, oxygenated solvent.

REFERENCES:
patent: 4301253 (1981-11-01), Warren
Bradley, J. Am. Chem. Soc., 101, No. 24, (1979), pp. 7419-7421.

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