Process for preparing alkanols and esters from synthesis gas

Details Process for preparing alkanols and esters from synthesis gas Process for preparing alkanols and esters from synthesis gas

1982-09-29

1984-03-13

Mars, Howard T.

Chemistry: fischer-tropsch processes; or purification or recover

Liquid phase fischer-tropsch reaction

518714, 502164, C07C 2706, C07C 2915

Patent

active

044368380

ABSTRACT:
This invention concerns a process for making alkanols and esters which comprises reacting a mixture of CO and H.sub.2 at a pressure of about 500 psig or greater and at a temperature of at least 150.degree. C. in the presence of a catalyst system comprising a ruthenium-containing compound, a second metal from Group IVB, VB, or VIB, consisting of a zirconium, titanium, vanadium or chromium-containing compound and a quaternary phosphonium salt, in the presence of an inert, oxygenated solvent.

REFERENCES:
patent: 4362821 (1982-11-01), Lin

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