Process for preparing aliphatic monocarboxylic acid ester of hyd

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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252430, 252472, 252473, 252474, C07C 6705

Patent

active

042244560

ABSTRACT:
Disclosed is a vapor phase catalytic oxidation process for preparing an aliphatic carboxylic acid ester of a monoaromatic compound having 1 to 2 hydroxymethyl substituents, such as benzyl acetate, p-methylbenzyl acetate, p-xylylenediacetate, benzyl propionate and benzyl butyrate. A gaseous feed comprised of a benzene compound having 1 to 2 methyl substituents, an aliphatic monocarboxylic acid having 2 to 4 carbon atoms and molecular oxygen is contacted with an improved catalyst. The metal ingredients of the catalyst consist essentially of (a) palladium, (b) arsenic and (c) at least one metal selected from alkali metals and alkali earth metals, and the atomic ratio of palladium:arsenic:the alkali or alkali earth metal is 1:0.05-4:0.1-10.

REFERENCES:
patent: 3547982 (1970-12-01), McKeon et al.
patent: 4033999 (1977-07-01), Onoda et al.

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