Process for preparing adduct of unsaturated alcohol and iodinate

Details Process for preparing adduct of unsaturated alcohol and iodinate Process for preparing adduct of unsaturated alcohol and iodinate

1991-07-14

1993-10-19

Cintins, Marianne M.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568848, C07C 3134

Patent

active

052547540

ABSTRACT:
An adduct of an unsaturated alcohol and an iodinated fluoroalkane is produced at a high conversion and high yield by reacting the unsaturated alcohol and the iodinated fluoroalkane in the presence of a radical catalyst and at least one additive selected from the group consisting of water, basic compounds, metal oxides, silver compounds and epoxy compounds.

REFERENCES:
patent: 3145222 (1964-08-01), Brace
patent: 4073817 (1978-02-01), Jager
patent: 4489006 (1984-12-01), Krahler
Chemical Abstracts, vol. 81, No. 25, Dec. 23, 1974, p. 510.
Park, et al., J. Org. Chem., 26, 2089, 1961.

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