Process for preparing acyl aminophenols

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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C07C23102

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active

056485352

ABSTRACT:
A process for the production of N-acylaminophenols by the concurrent hydrogenation of a nitrophenol to an aminophenol and the acylation of the aminophenol with acyl anhydride takes place on a continuous basis in a stirred tank reactor in which liquid product is continuously withdrawn from the reactor. Of particular interest is the manufacture of acetaminophen, N-acetyl-p-aminophenol by continuous reaction of p-ntirophenol, hydrogen and acetic anhydride.

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patent: 3383416 (1968-05-01), Benner
patent: 3917695 (1975-11-01), Schulman et al.
patent: 4264525 (1981-04-01), Huber, Jr.
patent: 4670589 (1987-06-01), Van Ness et al.
Method der Organischen Chemie (Houben-Weyl) vol. XI/1, 1957, George Thieme Verlag, Stuttgart, pp. 369-382.
Ullmann's Encyclopedia of Industrial Chemistry, vol. 84, 1992, "Stirred-Tank and Loop Reactors", Weinhe.
Ullmann's Encyclopedia of Industrial Chemistry, vol. A13, 1989, "Hydrogenation and Dehydrogenation".
CA(77): 126261u (1972) --Koengetal -"Catalytic Manufacture of p-acetamidophenol"--DE 1493727.
Derwent Abstract --Acc. #C66-F38223--"Production of Para-Acetamido-Phenol From Para-Nitrophenol"--DE 1493727.

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