Process for preparing acrylate compound

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

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C549S427000, C549S475000, C549S499000, C549S501000, C560S205000, C560S219000, C560S220000, C560S223000

Reexamination Certificate

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07148363

ABSTRACT:
An acrylate compound of formula (4):is produced by allowing an acrylic acid compound of formula (1):to react with an unsaturated compound of formula (2) or (3):In formulae (1) through (4), R1and R2are H or F, R3is H, F, or an alkyl, alkenyl, fluoroalkyl or fluoroalkenyl group, R4and R5are H, halogen, or an alkyl, alkenyl, halogenated alkyl or halogenated alkenyl group; and X and Y are an unsubstituted or substituted hydrocarbon group, and dashed line - - - means that X and Y may be bonded together to form a cyclic structure.

REFERENCES:
patent: 4293499 (1981-10-01), Hughes
patent: 4502494 (1985-03-01), Sprecker
patent: 48-39425 (1973-06-01), None
patent: 11-222460 (1999-08-01), None
patent: 2002-284739 (2002-10-01), None
patent: WO 81/00846 (1981-04-01), None
Yonezawa et al, “Reaction of Olefins with Acrylic Acid” Yuki Gosei Kagaku Kyokaishi, vol. 26(7), pp. 601-605 (1968). As Abstracted by Caplus.
Yonezawa et al, “The Reaction between Olefin and Acrylic Acid” Yuki Gosei Kagaku Kyokaishi, vol. 26(7), pp. 601-605 (Jul. 1968) English Translation.
Pavlov et al, Bulletin de la Societe Chimique de France, No. 12, pp. 2985-2986 (1974).
Ndong Mebah et al, “A convenient use of polyphosphoric acid in the esterification reaction between (meth)acrylic acid and (cyclo)alkenes” New Journal of Chemistry, vol. 17(12), pp. 835-841 (1993).

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