Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...
Patent
1990-12-17
1992-04-21
Garvin, Patrick P.
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Plural component system comprising a - group i to iv metal...
502 9, 502104, 502113, 526116, C08F 4685
Patent
active
051068052
ABSTRACT:
The present invention relates to a process for preparing a Ziegler-Natta type catalyst based on vanadium and titanium. The process comprises (1) contacting within a liquid hydrocarbon a spheroidal support comprising (i) MgCl.sub.2 free from any Mg-C bond and (ii) an electron-donor (D1) free from labile hydrogen, successively with an electron-donor (D2) containing labile hydrogen and then with an organometallic compound capable of reducing vanadium and titanium compounds, (2) washing of the solid product with a liquid hydrocarbon and (3) then contacting the washed solid product with a vanadium compound and a titanium compound, both being soluble in the liquid hydrocarbon. The catalyst consists of spheroidal particles without fines, is very active in olefin polymerization and is particularly suitable for producing elastomeric copolymers of propylene.
REFERENCES:
patent: 4612300 (1986-09-01), Coleman
patent: 4960741 (1990-10-01), Bailly et al.
Bailly Jean-Claud A.
Behue Patrick
BP Chemicals Limited
Garvin Patrick P.
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