Process for preparing a stabilized polyester

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

Reexamination Certificate

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Details

C528S287000, C528S298000, C528S302000, C528S308000, C528S308600, C428S035200, C428S035700, C428S036900

Reexamination Certificate

active

10472789

ABSTRACT:
The present invention discloses a process for the preparation of a stabilized polyester that is low in the generation of aldehydes which comprises reacting one or more diacids with one or more diols in an esterification process, and/or one or more diesters with one or more diols in a transesterification process in the presence of an effective amount of a stabilizer selected from the group consisting of (a) a polyhydric alcohol which is for example poly(ethylene-co-vinyl alcohol), poly(styrene-co-allyl alcohol), maltitol, isomalt, sorbitol, xylitol, sucrose, mucic acid dibutylester, mucic acid di(phenyl-1-ethyl)ester, pentaerythritol or dipentaerythritol; (b) a compound of the formula II, which is for example di-iso-octyl-phosphinic acid; (c) a sterically hindered amine which is for example Tinuvin 123 or Tinuvin 622; (d) a polyacrylamide or a cationic acrylamide copolymer; or (e) a hydroxyamine and/or a nitrone. Such polyesters, for example PET, when extrusion compounded exhibit a lower residual acetaldehyde content than does PET alone when similarly treated. The invention pertains to any polyester used in the manufacture of bottles or containers which in turn are used to store consumer materials, especially food, pharmaceuticals, beverages and most especially water

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Derwent Abstr. 1985-035365 [06] for JP 59230022 (1984).

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