Process for preparing a single phase Bi-containing superconducti

Superconductor technology: apparatus – material – process – High temperature – per se – Having tc greater than or equal to 150 k

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505732, 505730, 427 62, 427314, 427584, B05D 306, B05D 512

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052100707

ABSTRACT:
A process of preparing a superconducting thin oxide film includes irradiating a target containing Bi, Sr, Ca and Cu with a laser beam to prepare a thin film of superconducting Bi.sub.2 Sr.sub.2 Ca.sub.2 Cu.sub.3 O.sub.x oxide or a thin film of superconducting Bi.sub.2 Sr.sub.2 Ca.sub.1 Cu.sub.2 O.sub.y oxide on a substrate. The process is characterized in that the target containing Bi, Sr, Ca and Cu in an atomic ratio of 2:2:2:3 is positioned to face the substrate, and the laser beam is irradiated to the target in an atmosphere having an oxygen partial pressure of 0.01-1 Torr while the temperature of the substrate is maintained in a given temperature range suitable for growing the respective superconducting thin oxide films.

REFERENCES:
Applied Physics Letters, vol. 55, No. 20, Nov. 13, 1989, pp. 2123-2125, New York, US; Ivanov Z. et al: "Superconducting (Bi,Pb)-Ca-Sr-Cu-O Thin Films Prepared in Situ by Laser Ablation".
Applied Physics Letters, vol. 51, No. 8, Aug. 24, 1987, pp. 619-621, New York, US; D. Dijkkamp et al: "Preparation of Y-Ba-Cu Oxide Superconductor Thin Films Using Pulsed Laser Evaporation From High Tc Bulk Material".
Physica C, vol. 170, No. 5, Oct. 1, 1990, pp. 545-551, Amsterdam, NL; Brousse T., et al: "Laser Ablated Bismuth Cuprate Thin Films. Preparation and Effect of Oxygen Nonstochiometry Upon Superconductivity".
Ohya et al., "C-Axis Lattice Spacing Control of As-Grown Bi -Sr-Ca-Cu-O Thin Films by Single-Target Excimer Laser Ablation", Jpn. J. Appl. Phys. 28(6) Jun. 1989 pp. L978-L980.
Krebs et al., "Conditions for oriented growth of Y-Ba-Cu -O and Bi-Sr-Ca-Cu-O films by pulsed laser ablation", J. Appl. Phys. 69(4) Feb. 1991 pp. 2405-2409.

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