Process for preparing a platinum surface on tin oxide substrate

Chemistry: electrical and wave energy – Processes and products

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204 29, 204 47, C25D 350, C25D 534

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active

045526419

ABSTRACT:
A process for coating tin oxide with platinum which comprises soaking a tin oxide substrate in a strong caustic solution to activate the substrate, washing the substrate to remove all caustic solution, immersing the washed substrate in an alkaline solution containing Pt(OH).sub.6.sup..dbd. ions applying an electric potential of +0.1 to +0.7 volt to the immersed substrate, and recovering the substrate having a coating of platinum. This process is useful in preparing active platinum-coated catalysts using very small amounts of platinum.

REFERENCES:
patent: 3276976 (1966-10-01), Juliard
patent: 3340097 (1967-09-01), Hess et al.
patent: 4273624 (1981-06-01), Laitinen et al.
F. A. Lowenheim, Electroplating, McGraw-Hill Book Co., New York, 1978, pp. 298-300.
M. Watanabe, Preparation of Dispersed Platinum on Conductive Tin Oxide . . . , Journal of the Electrochemical Society, vol. 130, No. 1, Jan. 1963, pp. 59-64.

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