Process for preparing a melt-processable polyamide composition

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

Reexamination Certificate

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C528S312000, C528S315000, C528S318000, C528S323000, C528S326000

Reexamination Certificate

active

08080630

ABSTRACT:
The invention relates to a process for preparing a melt-processable polylactam by contacting caprolactam monomer with an anionic polymerization catalyst, polymerizing said monomer and contacting the resulting polylactam with a protic compound. The anionic polymerization catalyst is chosen from the group consisting of alkali-earth-metal-lactamates and alkali-earth-metal-lactamate forming compounds and the protic compound has a pKa larger than 14. The resulting polylactam has a good melt-stability and very low cyclic dimer content.

REFERENCES:
patent: 6528614 (2003-03-01), Kloosterman et al.
patent: 6809173 (2004-10-01), Schmid et al.
patent: 22 41 132 (1973-03-01), None
patent: 101 18 453 C 1 (2002-12-01), None
patent: 0 522 533 (1993-01-01), None
patent: 09-003187 (1997-01-01), None
K. Ueda et al, “Stabilization of High Molecular Weight Nylon 6 Synthesized by Anionic Polymerization of Epsilon-Caprolactam”; Polymer Journal, Society of Polymer Science; Tokyo, JP; vol. 28, No. 12; pp. 1084 1089; XP001079538.
Kohan, Melvin I,Nylon Plastics Handbook, MIK Associates, ISBN 1-56990-189-9, pp. 17-18 (1995).

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