Process for preparing a film having alternatively monolayers...

Coating processes – With post-treatment of coating or coating material – Plural film forming coatings wherein one coating contains a...

Reexamination Certificate

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C427S404000, C427S405000, C427S407100, C427S409000, C427S412100, C427S419300, C427S419500, C427S419700, C427S419800

Reexamination Certificate

active

10117788

ABSTRACT:
The present invention provides a process for preparing a thin film having alternating monolayers of a metal-metal bonded complex monolayer and an organic monolayer by layer-by-layer growth. The process comprises the steps of: (1) applying onto a surface of a substrate a first linker compound to produce a primer layer; (2) applying onto said primer layer a layer of a metal-metal bonded complex to produce a metal-metal bonded complex monolayer on said primer layer; (3) applying onto said metal-metal bonded complex monolayer a second linker compound; and optionally (4) sequentially repeating steps (2) and (3) at least once to produce said layer-by-layer grown thin film having alternating monolayers of a metal-metal bonded complex monolayer and an organic monolayer.

REFERENCES:
patent: 5217792 (1993-06-01), Chidsey et al.
patent: 5326626 (1994-07-01), Chidsey et al.
patent: 6128214 (2000-10-01), Kuekes et al.
patent: 6198655 (2001-03-01), Heath et al.
patent: 6314019 (2001-11-01), Kuekes et al.
patent: 6479240 (2002-11-01), Kayyem et al.
patent: 6646285 (2003-11-01), Kagan et al.
patent: 2001/0054709 (2001-12-01), Heath et al.
patent: 2002/0121314 (2002-09-01), Tao et al.
Haga et al., “Synthesis and Protein-Coupled Electron-Transfer Reaction of Self-Assembled Monolayers of a Ruthenium(II) Complex Containing Tridentate 2,6-Bis(benzimidazol-2-l)pyridine on a Gold Surface: Comparison of Acid/Base Chemistry with Bulk Solution Chemistry,” Inorg. Chem. 2000, 39, 4566-4573, Published on Web Sep. 13, 2000.
Forster et al., “Photostability, Electrochemistry, and Monolayers of [M(bpy)2(trans-1,2-bis(4-pyridyl)ethylene)L]+ (M = Ru, Os; L = Cl,H2O),” Langmuir 2002, 18, 2795-2799, Published on Web Feb. 23, 2002.
Nielsen et al., “Electron Transfer Reactions of Self-Assembled Monolayers of Thio(Phenylacetylene)n-Substituted Chiral Metal-Salen Complexes,” Langmuir 2002, 18, 2795-2799, Published on Web Feb. 3, 2002.
Varughese et al., “XPS Study of Self-Assembly of Ruthenium Dimers [((acac)2Ru)2bptz]0,+ on Hydrophobic and Hydrophilic SAMs,” Langmuir 2002, 18, 7964-7970, Published on Web Sep. 21, 2002.
Malcolm H. Chisholm, “One-Dimensional Polymers and Mesogens Incorporating Multiple Bonds Between Metal Atoms”, American Chemical Society, 2000.
Larry M. Hall, Robert J. Speer, and Helen J. Ridgway, “Synthesis and Antitumor ‘Activity’ of certain Rhodium(II)Carboxylates”, Institute of Molecular Medicine, vol. 10, No. 1, 1980.
Michael P. Doyle, “Chiral Dirhidium Carboxamidates: Catalysts for Highly Enantioselective Syntheses of Lactones and Lactams”, Trinity University
Daniel G. Nocera, “The Chemistry of Multielectron Excited States”, American Chemical Society, 1995.
Guang Cao, Hun-Gi Hong and Thomas E. Mallouk, “Layered metal Phosphates and Phosphates: From Crystals to Monolayers”, American chemical Society, 1992.
Gero Decher, “Fuzzy Nanoassemblies: Toward Layered Polymeric Multicomposites”, www.sciencemag.gov, vol. 277, Aug. 29, 1997.
Michael A. Ansell, Elizabeth B. Cogan and Catherine J. Page, “Coordinate Covalent Cobalt-Diisocyanide Multilayer Thin Films Grown One Molecular Layer at a Time”, American Chemical Society, Nov. 27, 1999.

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