Process for preparing a dimethylchlorosilane

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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C07F 708

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052527689

ABSTRACT:
A process for the preparation of dimethylchlorosilane by the redistribution reaction of dimethyldichlorosilane with at least one silane having Si-bonded methyl groups, hydrogen atoms and/or chlorine atoms in the presence of a catalyst, in which the silane is methylchlorosilane and/or methylsilane and the catalyst is a support which is insoluble in the reaction medium and to which NR.sub.2 R.sup.1 groups or .sup..crclbar. X.sup..sym. NR.sub.3 R.sup.1 groups are covalently bonded, in which R is the same or different and represents a hydrogen atom or a monovalent hydrocarbon radical having from 1 to 20 carbon atoms per radical, or two R radicals together represent a divalent hydrocarbon radical having from 4 to 11 carbon atoms, which is optionally interrupted by a hetero atom, R.sup.1 represents a divalent hydrocarbon radical having from 1 to 20 carbon atoms per radical and X.crclbar. represents a chloride ion, bromide ion or iodide ion.

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