Process for preparing a cycloalkanone and/or cycloalkanol

Details Process for preparing a cycloalkanone and/or cycloalkanol Process for preparing a cycloalkanone and/or cycloalkanol

1989-10-20

1991-04-02

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568835, C07D 4553

Patent

active

050048376

ABSTRACT:
The invention relates to a process for preparing a cycloalkanone and/or cycloalkanol by oxidation of a cycloalkane using oxygen to form a hydroperoxide, followed by a decomposition of the hydroperoxide, in the presence of an organic metal complex, the decomposition being carried out in the presence of a phthalocyanine or porphyrin metal complex immobilized on a carrier material.

REFERENCES:
patent: 4459427 (1984-07-01), Middleton et al.
patent: 4482746 (1984-11-01), Hermolin
patent: 4499305 (1985-02-01), Hermolin
patent: 4659829 (1987-04-01), Saussine et al.
"Mono-Oxygenase-Like Oxidation of Hydrocarbons Using Supported Manganese-Porphyrin Catalysts: Beneficial Effects of a Silica Support for Alkane Hydroxylation", J. Chem. Soc., Commun., 1989, pp. 1149-1151.

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