Process for preparing a cellllose acetoacetate alkanoates

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbohydrates or derivatives

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536 70, 536 71, 536 72, 536 73, 536 74, 536 75, C08B 306, C08B 102

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057707260

ABSTRACT:
The present invention relates to a process for preparing a substituted cellulose acetoacetate alkanoate without using a carboxamide/lithium chloride solvent system. The process involves contacting cellulose in a carboxylic acid diluent with an acetylating compound selected from the group consisting of a carboxylic acid anhydride and an acid chloride, an acetoacetylating compound selected from the group consisting of diketene, an alkyl acetoacetate and 2,2,6-trimethyl-4H-1,3-dioxin-4-one, and a mineral acid catalyst under conditions and in a molar ratio sufficient to cause the cellulose, acetylating compound and acetoacetylating compound to react to produce a substituted cellulose acetoacetate alkanoate.

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Staudinger and Eicher, Makromol. Chem., 1953, 10, 261-279.
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