Process for preparing 4-tert-butyloxycarbonyl-(S)-piperazine-2-t

Organic compounds -- part of the class 532-570 series – Organic compounds – Nitrogen attached directly or indirectly to the purine ring...

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544360, C07D24104

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active

057236151

ABSTRACT:
An improved process using chiral hydrogenation is described for the synthesis in high yields of a 4-protected-(S)-piperazine-2-tert-butyl-carboxamide, an intermediate for an HIV protease inhibitor.

REFERENCES:
Burk, et al., J. Am. Chem. Soc., 1993, 115:10125-10138.
Brunner, et al., Chem. Ber., 1992, 125:2085-2093.
Armstrong, et al., Tetrahedron Letters, 1994, 35(20):3239-3242.
Rossen et al, Tet. Lett. vol. 36, pp. 6419-6422 (Sep. 4, 1995).
Kanozia et al, Chemical Abstracts vol. 125, No. 142774 91996) (Abstract for DE 4446025, Jun. 27, 1996).
Landau et al, Journal of Catalysis 157 pp. 201-208 (1995).

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