Process for preparing 4-mercaptopyrrolidine intermediate compoun

Organic compounds -- part of the class 532-570 series – Organic compounds – Unsubstituted hydrocarbyl chain between the ring and the -c-...

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548544, C07D20724, C07D48704

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056294190

ABSTRACT:
An improved process for preparing a 4-mercaptopyrrolidine compound [I]: ##STR1## wherein R is H, lower alkyl or lower alkanoyl, R.sup.1 is H or SH-protecting group, and X is O or S, which comprises reacting halogenobutyric acid compound [VI], or a salt thereof, with amine compound [VII], or a salt thereof, and if necessary, followed by thiocarbonylating the product and/or removing the protecting group, said 4-mercaptopyrrolidine compound [I] being useful as intermediate for carbapenem antibacterial agents.

REFERENCES:
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Chemical Abstracts, vol. 82, No. 3, 20 Jan. 1975. Abstract No. 16463g.
Chemical Abstracts, vol. 98, No. 9, 28 Feb. 1983. Abstract No. 71602g.
Chemical Abstracts, vol. 98, No. 9, 28 Feb. 1983. Abstract No. 71842k.
Synthetic Methods of Organic Chemistry, vol. 14, pp. 234, 1960. No. 493.
Synthetic Methods of Organic Chemistry, vol. 19, pp. 400, 1965. No. 952.
"Ulmann's Encyclopedia of Industrial Chemistry", 5th edition, vol. A5, p. 247, point 12.3, 1986.

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