Process for preparing 4-chloro-2,5-dimethoxy aniline

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C 9314

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040828034

ABSTRACT:
The catalytic hydrogenation of 4-chloro-2,5-dimethoxy nitrobenzene can be performed in water with a nickel catalyst if the average particle size is below 0.1 mm. The resulting aniline is reacted with diketene and the so-obtained N-acetoacetyl derivative is an azoic coupling component.

REFERENCES:
patent: 1679211 (1928-07-01), Faber
patent: 2186722 (1940-01-01), Gubelmann et al.
Frey, "College Chemistry," second edition, pp. 305-307 (1958).
Deming, "General Chemistry," fourth edition, pp. 378 & 379 (1935).
Fierz-David and Blangey, "Fundamental Processes of Dye Chemistry," fifth edition, p. 377 (1949).

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