Process for preparing 4-amino-5-hexenoic acid

Details Process for preparing 4-amino-5-hexenoic acid Process for preparing 4-amino-5-hexenoic acid

1994-07-22

1995-08-08

Shippen, Michael L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Imidate esters

C07C24900

Patent

active

054400651

ABSTRACT:
This invention relates to a novel synthesis of 4-amino-5-hexenoic acid by thermal rearrangements, and to the novel intermediates produced thereby.

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Abstract-AAD89-05373, vol. 49/12-B of Dissertation Abstracts International, p. 5280; Tae Woo Kwon: "Part I. Asymmetric synthesis of 4-vinyl-4-aminobutyric acid. Part II. Section A-Thiophenyl cyclopropylcabinyl deriatives; conversion to dithiophenylcyclobutanes. Section B-Homoallylic substitution reactions"-1988-Assignee: The University of Connecticut.
Chemical and Pharmaceutical Bulletin, vol. 26, No. 3, pp. 774-783, Pharmaceutical Society of Japan; M. Watanabe et al.: "Ubiquinone and related compounds. XXXI. Synthesis os urinary metabolites of ubiquinone, phylloquinone, alpha-tocopherol and their relted compounds". Mar. 1978, Assignee: Takeda Chemical Industries.
JACS, vol. 98, No. 10, pp. 2901-2910; L. E. Overman: "A general method for the synthesis of amines by the rearrangement of allylic trichloroacetimidates. 1,5 transposition of alcohol and amine functions". May 1976-Assignee: University of California.
JACS, vol. 92, No. 3, pp. 741-743; W. S. Johnson et al.: "A simple stereo-selective version of the claisen rearrangement leading to transtrisubstituted olefinic bonds. Synthesis of squalene". Feb. 1970-Assignee: Stanford University.
Tetrahedron, vol. 44 No. 13, pp. 4243-4258 (1988)-G. Deleris et al.-"Direct regiospecific allylic amination via silicon induced pericyclic reactions. A novel synthesis of gamma vinyl gaba".
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