Process for preparing 3-alkylthiopropionic acid esters

Organic compounds -- part of the class 532-570 series – Organic compounds – Four or more ring nitrogens in the bicyclo ring system

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560152, 260 458NT, 260 4585H, C07D25134

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active

042269911

ABSTRACT:
A new process for preparing a polyhydric alcohol 3-alkyl-thiopropionate polyolefin resin stabilizer is provided, in which there is heated a reaction mixture containing a polyhydric alcohol, an alpha-olefin having 6 to 40 carbon atoms, and betamercaptopropionic acid or a lower alkyl betamercaptopropionate in the presence of an organic peroxide or azonitrile reaction initiator, and the polyhydric alcohol 3-alkylthiopropionate polyolefin resin stabilizer is recovered from the mixture.
Polyolefin resin compositions stabilized with the stabilizer prepared by the process of this invention, and stabilizer compositions comprising the stabilizer prepared by the process of this invention together with a phenol and/or an alkaline earth metal salt of a monocarboxylic acid are also provided.

REFERENCES:
patent: 3683048 (1972-08-01), Kolyer et al.
patent: 3707542 (1972-12-01), Steinberg et al.
patent: 3708543 (1973-01-01), Hickner et al.
patent: 3741909 (1973-06-01), Yamane et al.
patent: 3758549 (1973-09-01), Dexter et al.
patent: 4125516 (1978-11-01), Dexter et al.

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