Process for preparing 2,6-dichloropyridine

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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C07D21361

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054688647

ABSTRACT:
The present invention relates to a process for preparing 2,6-dichloropyridine which comprises reacting an organic solvent-free, catalyst-free reaction mixture comprising 2-chloropyridine and chlorine in the presence of a hydrogen chloride scavenger and ultraviolet light, and optionally in the presence of added moisture, at a temperature of between about 90.degree. C. and about 185.degree. C. Also claimed is a method for preventing calcium chloride plugging of the chlorine feed stream and for preventing calcium chloride build-up in the above reaction mixture which comprises adding moisture in the form of water or steam, or a combination thereof, to the reaction mixture prior to, or during, the reaction of said process.

REFERENCES:
patent: 3186994 (1965-06-01), Johnston et al.
patent: 3251848 (1966-05-01), Taplin, III
patent: 3557124 (1971-01-01), Stringham et al.
patent: 4054499 (1977-10-01), Kawamura
patent: 4701532 (1987-10-01), Humphreys et al.
patent: 4891108 (1990-01-01), Kilpatrick
patent: 5112982 (1992-05-01), Kamei
Chemical Abstracts 113:6172, 1990.
Chemical Abstracts 113:6173, 1990.
WPIDS 89-132582, 1989 of JP 01 075469 published Mar. 22, 1989.

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