Process for preparing 1-octene

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – From nonhydrocarbon feed

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Details

560244, 560265, 560227, C07C 1213

Patent

active

050307924

ABSTRACT:
This invention relates to a process for producing 1-octenes comprising reacting conjugated dienes and carboxylic acids in the presence of palladium, platinum or ruthenium catalysts to produce 2,7-alkadienyl esters, contacting the 2,7-alkadienyl esters with hydrogen to produce alkyl esters and subsequently pyrolyzing the alkyl esters to produce 1-octene and carboxylic acid.

REFERENCES:
patent: 3534088 (1970-10-01), Bryant et al.
patent: 3775469 (1973-11-01), Jung

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