Process for preparation of zeolite OE having an offretite type s

Details Process for preparation of zeolite OE having an offretite type s Process for preparation of zeolite OE having an offretite type s

1985-11-07

1987-08-18

Doll, John

Chemistry of inorganic compounds

Silicon or compound thereof

Oxygen containing

423328, 423330, 502 60, 502 77, C01B 3328

Patent

active

046876537

ABSTRACT:
Disclosed is a zeolite having a composition of the following formula: xM.sub.2
O.Al.sub.2 O.sub.3.(5-10)SiO.sub.2.yH.sub.2 O wherein M is at least one cation having a valency of n, and x is 0.8-2 and y is 0-10, and exhibiting an X-ray powder diffraction pattern shown in Table 1. This zeolite is prepared by a process wherein a reaction mixture comprising a silica source, an alumina source, an alkali source, a potassium source and water and having a composition satisfying the following molar ratios: SiO.sub.2 /Al.sub.2 O.sub.3 =6-40, OH/SiO.sub.2 =0.3-1, K.sub.2 O/M.sub.2 O=0.1-0.9 (M: the total of alkali metals), and H.sub.2 O/SiO.sub.2 =10-70, is crystallized at 120.degree. to 200.degree. C. with stirring. The zeolite is also prepared by a process wherein a granular amorphous aluminosilicate containing aluminum in an amount of 4 to 22 wt. % as Al.sub.2 O.sub.3 (on the anhydrous base), which is obtained by reacting an aqueous alkali metal silicate solution with an aqueous aluminum-containing solution, is incorporated in an aqueous alkali metal hydroxide solution and/or an aqueous alkali metal silicate solution, to form a mixture having a composition defined by the above-mentioned molar ratios, and the mixture is crystallized with stirring.

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