Process for preparation of trimethylsulfoxonium salts

Details Process for preparation of trimethylsulfoxonium salts Process for preparation of trimethylsulfoxonium salts

1985-03-11

1986-11-25

Daus, Donald G.

Organic compounds -- part of the class 532-570 series

Organic compounds

Sulfur containing

2605026, 260505R, C07C16100

Patent

active

046250654

ABSTRACT:
A method for the production of trimethylsulfoxonium salts is described in which trimethylsulfonium salts are oxidized with ruthenium tetroxide in the presence of an inert solvent to form the corresponding trimethylsulfoxonium salts.

REFERENCES:
patent: 2870163 (1959-01-01), Davis et al.
patent: 3534105 (1970-10-01), Distler et al.
patent: 4141920 (1979-02-01), Dryden, Jr. et al.
N. Milas et al., J.A.C.S., 58, pp. 1302-1304, (1936).
J. Courtney et al., Rev. Pure Appl. Chem. 1972, 22 (Jun.), 47-54, Ruthenium Tetraoxide Oxidations.
R. Kuhn et al., Justus Liebig's Annalen der Chemie, v. 611: 117-21 (1958), Trimethyl-Sulfoxonium Ion.

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