Process for preparation of poly(aryl ether) polymers by macro mo

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate

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528126, 528128, 528171, 528174, 528175, 528219, 528220, C08G 802, C08G 1400, C08G 6540

Patent

active

052350193

ABSTRACT:
An improved process for the preparation of poly(aryl ether) polymers by reacting, in the absence of dipolar aprotic solvents, an alkali metal double salt of a dihydric phenol with a dihalobenzenoid compound in the presence of a macrocyclic polyether compound having one ether ring in which oxygen atoms are separated one from the other by 2 to 3 carbon atoms, the ring having fused thereto from 0 to 4 monocyclic or polycyclic aromatic or saturated hydrocarbon nuclei. The nuclei are attached by vicinal carbon atoms thereof to adjoining ring oxygens in oxygen-carbon-carbon-oxygen arrangement.
The poly(aryl ether) polymer resins produced by the process have a low degree of coloration and excellent mechanical and electrical properties which allow them to be molded into a variety of articles.

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