Process for preparation of para-divinylbenzene

Chemistry of hydrocarbon compounds – Plural serial diverse syntheses – To produce aromatic

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585440, 585469, C07C 228, C07C 714

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active

049820303

ABSTRACT:
There is provided a method for preparing para-divinylbenzene by dehydrogenating para-diethylbenzene followed by crystallizing para-divinylbenzene. The para-diethylbenzene may be prepared by alkylating ethylbenzene with ethylene in the presence of a para-selective molecular sieve catalyst, such as ZSM-5 modified with an oxide of magnesium and, optionally, an oxide of phosphorus.

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W. W. Kaeding, Sharp-Selective Reactions with Zeolite Catalysts V. Alkylation or Disproportionation of Ethylbenzene to Produce P-Diethylbenzene, from Journal of Catalysis, vol. 95, No. 2, Oct. 1985.

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