Process for preparation of .OMEGA.-alkenylchlorosilanes

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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C07P 708

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active

052064026

ABSTRACT:
The present invention is a process for the preparation of omega-alkenylchlorosilanes. The process comprises reacting a mixture comprising an .alpha.,.OMEGA.-diene and an organohydrosilane in the presence of a supported platinum catalyst to form an .OMEGA.-alkenylchlorosilane, where the mole ratio of the .alpha.,.OMEGA.-diene to the organohydrosilane is within a range of about 6:1 to 50:1. A preferred process is run as a continuous process employing a fixed-bed of silica gel supported platinum catalyst and excess .alpha.,.OMEGA.-diene is recovered and recycled to the process.

REFERENCES:
patent: 2632013 (1953-03-01), Wagner
patent: 2637738 (1953-05-01), Wagner
patent: 2721973 (1955-10-01), MacKenzie et al.
patent: 2851473 (1958-09-01), Wagner
patent: 3159662 (1964-12-01), Ashby
patent: 5041595 (1991-08-01), Young et al.

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