Process for preparation of nitrous oxide

Chemistry of inorganic compounds – Nitrogen or compound thereof – Oxygen containing

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423400, 423403, C01B 2126

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active

058492577

ABSTRACT:
A process for preparation of nitrous oxide, wherein ammonia is reacted with oxygen in the presence of steam using a copper-manganese oxide catalyst having diffraction angles measured by X-ray diffraction analysis of about 36.degree., about 58.degree. and about 64.degree.; a copper-manganese oxide catalyst suitable for the process. The catalyst is highly active and selective, has a long catalyst-lifetime, gives a non-condensable gas comprising nitrogen, oxygen and nitrous oxide which contains nitrous oxide in a high concentration, and is less deteriorative. The catalyst can be used in a process for preparation of nitrous oxide in which formation of NOx as by-products is reduced; and a process for stably recovering nitrous oxide.

REFERENCES:
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Y. Suwa et al, Kogyo Kagaku Zassi, 64, 1879-1888 (1961).
JACS 43 1982-1987 (1921).
Ann. Chim. Fr. (Paris), 3, 429-452 (1978).
Bull. Soc. Chim. Fr., 9-10, I-363-364 (1980).
J. Chim. Phys., Phys. Chim. Biol., 86, 1889-1915 (1989).
ICDD, Powder Diffraction File, Alphabetical Indexes Inorganic Phases Sets 1-45 (1995).

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