Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1980-05-02
1981-10-06
Lone, Werren B.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
568576, C07C179035
Patent
active
042937205
ABSTRACT:
Disclosed is a process for the preparation of hydroperoxides comprising liquid-phase oxidizing an aromatic compound having a secondary alkyl group with molecular oxygen in the presence of a basic aqueous solution and a copper compound catalyst, wherein an aqueous solution containing (A) cupric carbonate and (B) an alkali metal carbonate and/or an alkali metal bicarbonate is prepared outside the oxidation system and this aqueous solution is supplied to the oxidation system.
According to the process, even under basic conditions, inactivation of the catalyst owing to precipitation is prevented, and the intended aromatic hydroperoxide can be obtained at a high oxidation speed.
REFERENCES:
patent: Re23916 (1954-12-01), Lorand et al.
patent: 2655545 (1953-10-01), Bruning et al.
patent: 3803243 (1974-04-01), Brownstein et al.
Iwaki Tetsuo
Kaneko Hisamitsu
Moriuchi Shuji
Takahashi Yukio
Lone Werren B.
Mitsui Petrochemical Industries Ltd.
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