Process for preparation of half-vanadocene compound

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

Reexamination Certificate

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C502S103000, C502S117000, C526S160000, C526S943000

Reexamination Certificate

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06849753

ABSTRACT:
A process for preparing a half-vanadocene compound, the process comprising reacting chlorine gas with a vanadocene compound represented by the formula (1)in-line-formulae description="In-line Formulae" end="lead"?Cp2VX2  (1)in-line-formulae description="In-line Formulae" end="tail"?wherein Cp represents cyclopentadienyl, substituted cyclopentadienyl, indenyl, substituted indenyl, fluorenyl, substituted fluorenyl, benzoindenyl, substituted benzoindenyl, azulenyl or substituted azulenyl, and the two Cp groups may be the same or different, X represents fluorine, chlorine, bromine or iodine and the two X atoms may be the same or different.

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Z. Naturforsch “Oxochlorination of Transition Metal Complexes with Thionyl Chloride,” pp. 153-156 1998.
Tr.Khim.Khim.Tekhnol, “Reaction of vanadocene with tert-butylhydroperoxide and tert-butylper benzoate,” 4 , pp.32-34 1974.
K.H. Thiele, et al., “Contributions to the Chemistry of Transition Metal Alkyl Compounds, XIX. On the Preparation and Properties of Cyclopentadienyl Vanadium Trichloride,” Z.Anorg. Allg. Chem. 423, pp.231-234 1976.

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