Process for preparation of cyclododecanone

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Reexamination Certificate

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C568S347000, C568S348000, C568S375000

Reexamination Certificate

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06861563

ABSTRACT:
In the process for producing a cyclododecanone by isomerizing an epoxycyclododecane-containing starting material in the presence of an isomerization reaction catalyst containing lithium bromide and/or lithium iodide, in order to perform the reaction with high efficiency (high reaction rate) and high selectivity and stably produce a high-purity cyclododecanone in industry while maintaining a high-level reaction rate, the epoxycyclododecane-containing starting material is produced by contacting an epoxycyclododecadiene with hydrogen in the presence of a hydrogen-reduction catalyst and has a content of the hydroxyl group-containing cyclododecane compounds contained in the epoxycyclododecane-containing starting material controlled to 5 mol % or less.

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patent: 6204416 (2001-03-01), Liedloff
patent: 6335472 (2002-01-01), Matsuzaki et al.
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patent: 6417404 (2002-07-01), Sugise et al.
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Zh. Org. Khim, 26(7), 1497-1500 (1990) [Document in Russian].

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