Process for preparation of aromatic sulfone compounds

Organic compounds -- part of the class 532-570 series – Organic compounds – Sulfur containing

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568 28, 562828, C07C14706

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049507931

ABSTRACT:
An aromatic hydrocarbon represented by the following general formula [I]: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 stand for a hydrogen atom or alkyl group, is reacted with a halogenated sulfonic acid in the presence of a Lewis acid to obtain an aromatic sulfone compound represented by the following general formula [II]: ##STR2## wherein R.sub.1, R.sub.2 and R.sub.3 are as defined above and Z stands for a halogen atom or an aromatic hydrocarbon group represented by the following general formula [III]: ##STR3## in which R.sub.1, R.sub.2 and R.sub.3 are as defined above.

REFERENCES:
patent: 2781402 (1957-02-01), Chadwick
patent: 3579590 (1971-05-01), Davis
Graybill, Bruce M. "The Synthesis of Aryl Sulfones," Journal of Organic Chemistry, vol. 32, (Sep. 1967), pp. 2931-2933.
Tyobeka, Themba E., et al., "Novel Sulphonylating reagent: Sulphuric Acid-Hexafluoroacetic Anhydride," J. C. S. Chem. Comm., (1980), pp. 114-115.
Sipes, Herbert J., Jr., et al., "An Improved Synthesis of Aryl Sulfones," Synthesis, (Mar. 1984), pp. 283-284.
Ueda, Mitsura, et al., "A New Synthesis of Diaryl Sulfones," Synthesis, (Apr. 1984), pp. 323-325.

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