Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1976-06-09
1977-12-20
Wyman, Daniel E.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
C07C 8502
Patent
active
040641716
ABSTRACT:
In the catalytic reaction of cyclohexane or an alkylated cyclohexane with ammonia to produce aniline or an alkylated aniline, the presence of water is beneficial in increasing the amount of aromatic amines produced, or in reducing the amount of undesired by-products, or both. The amount of water is 1 to 70 mole percent based on the total amount of the cyclohexane reactant and water used. The catalysts used are exemplified by zinc oxide, titanium oxide, etc.; metal compounds such as vanadates, molybdates and titanates; and cadmium sulfide, zinc selenide and the like.
REFERENCES:
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patent: 3931298 (1976-01-01), Wollensak
patent: 4001260 (1977-01-01), Del Pesco
Dadashev, CA 81:3397t (1974).
Dadashev et al., CA 69:99832g (1968).
E. I. Du Pont de Nemours and Company
Mentis Anthony P.
Waltz Thomas A.
Wyman Daniel E.
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