Process for preparation of alcohols by hydration of olefins

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 2904

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045284105

ABSTRACT:
Olefins are hydrated to the corresponding alcohols in the presence of at least one crystalline alumino-silicate selected from offretite, ferrierite and erionite. The offretite, ferrierite and erionite are preferably characterized by X-ray diffraction patterns shown in Tables 1 and 7; Tables 2, 8 and 9; and Table 3, respectively. At least a part of the exchangeable cations in the offretite, ferrierite and erionite may be exchanged with at least one cation selected from a hydrogen ion, an alkaline earth metal ion and a rare earth metal ion. Furthermore, at least a part of the exchangeable cations in the erionite may be exchanged with an ammonium ion and/or an alkali metal ion.

REFERENCES:
patent: 4214107 (1980-07-01), Chang et al.

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