Chemistry of hydrocarbon compounds – Aromatic compound synthesis – Having alkenyl moiety – e.g. – styrene – etc.
Patent
1991-05-22
1993-03-02
Reamer, James H.
Chemistry of hydrocarbon compounds
Aromatic compound synthesis
Having alkenyl moiety, e.g., styrene, etc.
568808, 568814, 568319, 568323, C07C 124
Patent
active
051911337
ABSTRACT:
The selective formation of 2-acetonaphthalene is achieved by acetylating naphthalene in the presence of liquid hydrogen fluoride. The 2-acetonaphthalene can be separated from the formed 1-acetonaphthalene isomer by successive hydrogenation of the isomer mixture and dehydration. The hydrogenation is selective to the 2-isomer while the 1-acetonaphthalene remains unreacted. Upon completion, 2-vinylnaphthalene can be distilled off from the unreacted 1-acetonaphthalene.
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Cassady D. R.
Frenkel S. D.
Hoescht Celanese Corporation
Reamer James H.
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