Process for preparation for alkanolamine, catalyst used in the p

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564475, C07C20916

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active

055999999

ABSTRACT:
A process is provided which comprises using a catalyst comprises a rare earth element supported on an inorganic heat-resisting carrier, when a monoethanolamine is selectively prepared by reacting an alkylene oxide with ammonia in a liquid phase. This catalyst has excellent monoalkanolamine selectivity and heat resistance; and therefore, even when the ratio of ammonia to the alkylene oxide is lower compared with cases where other catalysts are used, an equal or more amount of the monoalkanolamine can be formed, and thus the recovery cost of the unreacted ammonia is reduced. Further, since the total amount of the feed raw materials is reduced, apparatuses for the reaction system and recovery system can be made smaller, and thus the cost of equipment is reduced.

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patent: 5210325 (1993-05-01), Kemp et al.
patent: 5395973 (1995-03-01), Washington et al.
Industrial and Engineering Chemistry, Product Research and Development, (1986), 25:424-430.
"Ion-Exchange--Introduction on Theory and Practice", (1981), Maruzen Co., Ltd., p. 34.

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